1,3 di imino iso indoline

To find highly efficient photocatalysis materials,complex iron(Ⅱ) 1,4-dithiin-diphenyl porphyrazine(FePzPh(dtn)4) and its sulfonation derivatives(FePzSPh(dtn)4) were synthesized from 2,3-dithiolate-1,4-dithiin and 1,3-diiminoisoindoline by solid-state method using ammonium molybdate as a catalyst in the presence of ferrous sulfate heptahydrate.

為尋求更高效的光催化劑,以1,3-二亞氨基異吲哚啉和2,3-二氰基-1,4-二噻英為原料,鉬酸銨為催化劑,七水合硫酸亞鐵為模板,用固相法合成了二(1,4-二噻英)-二苯基四氮雜卟啉鐵(FePzPh(dtn)4),并對其進行了磺化改性(FePzSPh(dtn)4)。

To improve the solubility properties and find highly efficient photocatalysis materials,the assymmetric iron(Ⅱ) 1,4-dithiin-diphenyl porphyrazine FePcPz(dtn)4 and its chloridized,FePcClPz(dtn)4 were synthesized from 2,3-dithiolate-1,4-dithiin and 1,3-diiminoisoindoline by solid-state method.

為改善催化劑的溶解性能,以尋求更高效的光催化劑,以1,3-二亞氨基異吲哚啉和2,3-二氰基-1,4-二噻英為原料,用固相法合成了不對稱型1,4-二噻英-二苯基四氮雜卟啉鐵FePcPz(dtn)4及其氯代改性FePcClPz(dtn)4。

Then 1,3-diiminoisoindolium nitrate was neutralized with sodium hydroxide to afford 1,3-diiminoisoindoline.

以硬脂酸和油酸為乳化劑、鉬酸銨為催化劑,尿素和鄰苯二甲酸酐經亞氨化,然后在硝酸銨存在下發生縮合反應得到1,3-雙亞氨基異吲哚啉的硝酸鹽,最后用氫氧化鈉中和得到1,3-雙亞氨基異吲哚啉。